Diketahui glukosa(mr=180) dan natrium sulfat(mr=142)masing masing 2 di larutkan dalam 100 gram air (kb=0,5 dan kf=1,86)tentukan titik didih dan titik beku larutan
Jawaban:
natrium sulfat
Tb larutan = 104,35°C
Tf larutan = -16,182°C
glukosa
Tb larutan = 102,75°C
Tf larutan = -0,23°C
Penjelasan:
Diketahui:
misalkan
massa glukosa = 100 gram
massa natrium sulfat = 100 gram
p = 100 gram
Kb = 0,5°C/m
Kf = 1,86°C/m
Ditanyakan:
Tb larutan
Tf larutan
Jawab:
Natrium sulfat = Na₂SO₄
Na₂SO₄ —> 2Na⁺ + SO₄²⁻
n = 3
ΔTb = m/Mr x 1000/p x Kb x i
ΔTb = 100/342 x 1000/100 x 0,5 x i
ΔTb = 0,29 x 10 x 0,5 x 3
ΔTb = 4,35°C
Tb larutan = 100 + ΔTb
Tb larutan = 100 + 4,35
Tb larutan = 104,35°C
ΔTf = m/Mr x 1000/p x Kb x i
ΔTf = 100/342 x 1000/100 x 1,86 x i
ΔTf = 0,29 x 10 x 1,86 x 3
ΔTf = 16,182°C
Tf larutan = 0 – ΔTf
Tf larutan = 0 – 16,182
Tf larutan = -16,182°C
Glukosa
ΔTb = m/Mr x 1000/p x Kb
ΔTb = 100/180 x 1000/100 x 0,5
ΔTb = 0,55 x 10 x 0,5
ΔTb = 2,75°C
Tb larutan = 100 + ΔTb
Tb larutan = 100 + 2,75
Tb larutan = 102,75°C
ΔTf = m/Mr x 1000/p x Kb
ΔTf = 100/180 x 1000/100 x 1,86
ΔTf = 0,55 x 10 x 1,86
ΔTf = 10,23°C
Tf larutan = 0 – ΔTf
Tf larutan = 0 – 10,23
Tf larutan = -0,23°C
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